Ammonium polyphosphate
- Createtime: 2026-04-14
- Updatetime: 2026-04-15
Product Details
| useage |
Industrial use
|
| deliveryInfo |
|
| appearance |
powder
|
| aliasen |
|
| supplyCapacity |
50000MT/Month
|
| harbor |
Qingdao,China
|
| pH |
4.5–6.5
|
| minorder |
1KG
|
| Appearance |
White/off-white crystalline powder
|
Shandong Huashang Chemical Co., Ltd. is a high-tech enterprise focused on industry of fine chemicals research and develop, produce and sale. Shandong Huashang Chemical Co., Ltd. is located in Shan Dong Ji Nan China. we have the ability to provide you high quality products. More than 90 % of our products are exported to developed countries and regions such as north America, Europe, Japan, South Korea and the Middle East.
Product Overview
Ammonium polyphosphate (APP) is an inorganic polymeric phosphate salt with phosphorus-nitrogen synergistic flame retardant properties. It appears as white or off-white crystalline powder, non-toxic, odorless, and halogen-free. As a high-efficiency environment-friendly flame retardant, it is widely used in intumescent coatings, plastics, rubber, and construction materials. The product is available in low/medium/high polymerization grades; high-polymerization (Phase II, n>1000) is the mainstream for industrial use due to low water solubility and high thermal stability.
Product Features
- High Purity & Stability: P2O5 ≥68%, N ≥13%; thermal decomposition temperature >250°C.
- Halogen-Free & Low Smoke: Non-toxic, low corrosion, minimal smoke release during combustion.
- Controllable Solubility: Low polymerization (n<20) water-soluble; high polymerization (n>20) water-insoluble.
- Good Compatibility: Easily blended with carbon sources (e.g., pentaerythritol) and blowing agents.
- Strict QC: COA, MSDS, TDS provided; complies with EU REACH and RoHS.
Physical & Chemical Properties
Physical Properties
- Appearance: White/off-white crystalline powder
- Molecular Formula: (NH4)n+2PnO3n+1 (n=30–1000)
- Purity: P2O5 ≥68%, N ≥13%
- Density: 1.74 g/cm3 (20°C)
- pH Value: 4.5–6.5 (10% aqueous solution)
- Solubility: High polymerization: <0.1 g/100 mL (25°C, water)
- Decomposition Temperature: >250°C
- Moisture Content: ≤0.5%
Chemical Properties
- Flame Retardant Mechanism: Releases polyphosphoric acid at high temperature, promoting char formation; expands into a porous carbon layer to insulate oxygen and heat.
- Stability: Stable in dry air; hydrolyzes slowly in moisture; decomposes above 250°C releasing NH3.
- Incompatibility: Avoid strong bases, strong oxidants, and prolonged moisture exposure.
Applications
- Intumescent Fire Coatings: For steel structures, wood, and building materials (main acid source).
- Plastics & Polymers: PP, PE, EVA, PU foams, and thermoplastics (halogen-free flame retardant).
- Construction Materials: Fireproof boards, insulation materials, and sealants.
- Textiles & Paper: Flame retardant treatment for cotton, linen, and paper products.
- Agriculture: Slow-release nitrogen-phosphorus fertilizer (low polymerization grade).
Storage & Transportation
Storage
- Conditions: Cool, dry, ventilated warehouse; tightly sealed to prevent moisture and caking.
- Temperature: 10–25°C; avoid direct sunlight and high humidity.
- Shelf Life: 24 months (original packaging).
Transportation
- Classification: Non-hazardous goods.
- Packaging: 25kg/bag (inner plastic, outer woven); 500kg/1000kg big bag optional.
- Precautions: Avoid collision, extrusion, rain, and moisture; do not mix with oxidants.
Operation Notes
- Wear dust mask, safety goggles, and chemical-resistant gloves.
- Operate in well-ventilated areas; avoid dust inhalation.
- In case of skin/eye contact, rinse with plenty of water immediately.
Regulatory Information
- EINECS: 269-789-9
- HS Code: 28353990
- Compliance: REACH, RoHS, GB 14907-2018 (fire coatings)
Full Parameter Table
| Item | Specification |
| Product Name | Ammonium Polyphosphate (APP) |
| CAS NO. | 68333-79-9 |
| IUPAC Name | Ammonium polyphosphate |
| Synonyms | APP, Polyphosphoric acids ammonium salts |
| Molecular Formula | (NH4)n+2PnO3n+1 |
| Purity | P2O5 ≥68%, N ≥13% |
| Appearance | White crystalline powder |
| pH | 4.5–6.5 |
| Solubility (25°C) | High polymerization: <0.1 g/100 mL |
| Decomposition Temp | >250°C |
| Packaging | 25kg/bag; 500kg/1000kg big bag |
| Grade | Industrial Grade / Flame Retardant Grade |
| Shelf Life | 24 months |