Shandong Huashang Chemical Co., Ltd.
Product
1-METHYL-1-CYCLOHEXENE
  • Brand:HS
  • Model:25kg/drum
  • Purity:99%
  • Cas:591-49-1
  • Createtime: 2026-04-14
  • Updatetime: 2026-04-15
Product Details
useage Industrial use
deliveryInfo
appearance liquid
Molecular Weight 96.17
aliasen
supplyCapacity 50000MT/Month
harbor Qingdao,China
minorder 1KG
Appearance Colorless liquid, no visible impurities

Shandong Huashang Chemical Co., Ltd. is a high-tech enterprise specializing in the research and development, manufacturing, and sales of fine chemicals. Headquartered in Jinan, Shandong, China, we are committed to delivering high-quality products to our global partners. Currently, over 90% of our products are exported to developed markets, including North America, Europe, Japan, South Korea, and the Middle East.

Product Description

1-METHYL-1-CYCLOHEXENE (CAS: 591-49-1), also known as α-methylcyclohexene, is a colorless, flammable cyclic olefin. It is a versatile organic intermediate widely used as a solvent, monomer precursor for polymer modification, and research reagent for studying alkene stereochemistry.

Molecular Formula & Structure

Molecular Formula: C?H??; Molecular Weight: Approximately 96.17

Physical Properties

  • Appearance: Colorless liquid
  • Melting Point: Approximately -120.4 °C; Boiling Point: Approximately 110–111 °C (lit.)
  • Density: Approximately 0.811 g/cm3 (20 °C, lit.); Refractive index: 1.45 (20 °C)
  • Solubility: Miscible with ethanol, ether and hydrocarbons; slightly soluble in water (52 mg/kg at 25 °C)
  • Stability: Stable under normal conditions; may polymerize; highly flammable, flash point -4 °C (closed cup)

Chemical Properties

  • CAS Number: 591-49-1; EINECS Number: 209-718-0; Chemical Type: Cyclic olefin, organic intermediate
  • Chemical Characteristics: Contains a cyclohexene ring with a methyl substituent on the double bond; undergoes electrophilic addition reactions following Markovnikov's rule.
  • Applications: Solvent; organic synthesis intermediate; research reagent for studying alkene reactions and secondary organic aerosol yields.
  • Toxicity: Irritating to eyes, respiratory tract and skin; oral toxic, may damage lungs; harmful to the environment.

Synthesis Method

  • Raw Materials: 1-methylcyclohexanol (main raw material), sulfuric acid/phosphoric acid (catalyst); or 1-methylcyclohexyl bromide and sodium ethoxide.
  • Synthesis Route: Mainly via acid-catalyzed dehydration of 1-methylcyclohexanol (E1 elimination) or base-induced dehydrohalogenation of 1-methylcyclohexyl bromide (E2 elimination).

Storage & Safety

  • Storage: Sealed, stored at room temperature in a cool, dry place; avoid sunlight, high temperature and moisture; stabilize with 10 ppm hydroquinone if needed.
  • Safety: Wear protective equipment; avoid contact and ingestion; keep away from fire sources and oxidants.
  • Hazard: Highly flammable liquid; decomposes when heated; may cause environmental pollution if leaked.